The molecular and electronic structures of a thioaroyl cation formed by borinium ion-mediated C=S double bond cleavage of CS2.
نویسندگان
چکیده
The first crystallographic and electron density distribution analyses of a thioaroyl cation unveil its true structural perspective; this chemical species can be mainly expressed as the combination of the thioketene form (II) and sulfonium form (III) with a C≡S(+) triple bond character.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 69 شماره
صفحات -
تاریخ انتشار 2015